Chace Crawford as Nate Archibald, Blake Lively as Serena van der Woodsen, and Ed Westwick as Chuck Bass in the Season 5 premiere episode of "Gossip Girl."

Chace Crawford as Nate Archibald, Blake Lively as Serena van der Woodsen, and Ed Westwick as Chuck Bass in the Season 5 premiere episode of "Gossip Girl."