Vanessa Williams stars as Wilhelmina Slater in Ugly Betty.ABC/Bob D'Amico - Monday, October, 1, 2007, 7:1 PM

Vanessa Williams arrives at the 59th Annual Primetime Emmy Awards at the Shrine Auditorium on September 16, 2007 in Los Angeles, California.Jeff Vespa/WireImage.com - Monday, September, 17, 2007, 1:17 AM

Vanessa Williams at the 13th Annual Screen Actors Guild Awards.Steve Granitz/WireImage.com - Monday, January, 29, 2007, 8:29 PM

Tim Allen and Vanessa Williams at the 64th annual Golden Globe Awards.NBC/Paul Drinkwater - Tuesday, January, 16, 2007, 9:16 AM

Tim Allen and Vanessa Williams at the 64th annual Golden Globe Awards.NBC/Paul Drinkwater - Tuesday, January, 16, 2007, 9:16 AM

Vanessa Williams at the 64th annual Golden Globe Awards.Steve Granitz/WireImage.com - Monday, January, 15, 2007, 11:15 PM

2007 Emmy Awards: Vanessa Williams nominated for Best Supporting Actress (Comedy) for her role as Wilhelmina Slater in Ugly Betty.ABC/Andrew Eccles - Wednesday, September, 20, 2006, 9:20 PM